LF - So, kind of scrap some of the things I said before ... at least about cycling. I got in my car last night about 7 pm. After heating soaking the car from lots of hard work, but not running the A.C. I turned on the A.C. for my maneuvers around in the driveway and sure enough, it cycled. I'm about 90% sure that's what it was doing. I can't say for sure why. The A.C. system wasn't used during my 225 mile towing event, but even though it was not, I would think the system would be warmed up from all the residual heat under the hood. However, I could be wrong. Perhaps the compressor was still quite cool, and firing it up at that time, the whole system wasn't fully warmed up. Just a big crap shoot and I'm only speculating.
As for the charge in your system, I don't think you should concern yourself about overcharging (with where your system is now). The high pressure side will shut the system off if it sees too much pressure. As for the pressures you're seeing and the confusion ... that's why trying to judge your system via pressure is not the best way. The low numbers you are seeing on the low side are really the only numbers you should consider important.
I would have to say that if the low side pressure switch shuts things down at say (this is a guess) 26 psi, having it run at 28 to 30 psi is optimal. You want it to be fairly close to the low side shut off. It being in a low pressure zone while operating DOES NOT NECCESARILY mean it is low on capacity. You're doing everything right, as far as I can see.
My system also increases temp somewhat at idle. So I wouldn't be so concerned about that either. That valve reset sounds interesting. I'll want to learn more about that.
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View my fuel log 2020 Mirage ES 1.2 manual: 42.4 mpg (US) ... 18.0 km/L ... 5.5 L/100 km ... 51.0 mpg (Imp)